I had an early Toyota did the same thing. When the t/c and trans are "mated" there is a seal between the two to keep each unit's fluid where it belongs.
Probably have to split the two and replace the seal. While you are in there check the breathers on both trans and t/c. The trans heats up more than the t/c and if the breather is plugged then it will build pressure and push the fluid into the transfer case.
Fix it soon or you may be doing a trans re-build soon.
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